Abstract:
Solid waste landfills constitute a potential major threat to groundwater quality. Water present in the waste, rainwater infiltration during and/or after the landfilling process and groundwater penetration can result in the generation of leachate. Leachate is a kind of waste liquid consisting of waste contaminants. Clay soils are natural matters to minimize the permeability of natural soil liners in landfill areas. Some contaminants in the leachate can alter compacted clay soils and cause increasing or decreasing permeability.
This study investigates effects of leachate on the permeability of the compacted and consolidated clay soils, thereby evaluating the effectiveness of these clay soils as liners in preventing groundwater contamination. To determine removal capability of compacted and consolidated clay soils, some metal ions (Fe(II), Mn(II)) are also measured in influent and effluent of the lab-scale reactor.
According to results of this study, Fe(II) and Mn(II) removal efficiency increases with time. Fe(OH)3 and MnO2 precipitations on the clay soil particles increase oxidation rate depending on the autocatalytic effect. Also, in the beginning, some decrease has been observed in the compacted and consolidated clay soils permeability associated with the contamination. However, as time goes by, these results show that leachates may cause an increase in the permeability.